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Properties of Trichlorosilane (TCS)

Basic Physical Properties of Trichlorosilane

Trichlorosilane is produced by blowing hydrogen chloride through a bed of silicon powder at 300°C. There, they combine to make Trichlorosilane and hydrogen according to the chemical equation:
Si + 3 HCl → SiHCl3 + H2
 
Chemical Structure:
 

Properties  
   
Molecular Formula SiHCl3
Relative Density 1.342 g/cm³
Relative Gas Density (air = 1) 4.7
Refractive Index 1.4020
Melting Point - 126.5°C
Boiling Point 31.8°C
Flash Point (open cup) - 13.9°C
Saturated Vapor Pressure (14.5°C) 53.33 kPa
Specific Heat Capacity 0.96 J/(g.°C)
Heat Evaporation 195.4 J/g
Critical Point 5.11 atm - 56.6°C
Critical Temperature 234°C
Critical Pressure 3.63 MPa
Surface Tension 14.3 1x10³N/m
Kinematic Viscosity (25°C) 0.23 mm²/s
Expansion Coefficient 0.0019
Spontaneous Ignition Temperature 175°C
Lower Explosion Level 6.9 %
Upper Explosion Level 70 %
Dipole Moment 0.97
Heat of Formation - 482 kJ/mol
   
   

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